Send File Attachment from Form Using phpMailer and PHP

Try:

if (isset($_FILES['uploaded_file']) &&
    $_FILES['uploaded_file']['error'] == UPLOAD_ERR_OK) {
    $mail->AddAttachment($_FILES['uploaded_file']['tmp_name'],
                         $_FILES['uploaded_file']['name']);
}

Basic example can also be found here.

The function definition for AddAttachment is:

public function AddAttachment($path,
                              $name="",
                              $encoding = 'base64',
                              $type="application/octet-stream")