You could have them semi-colon delimited in a single value, e.g.
App.config
<add key="paths" value="C:\test1;C:\test2;C:\test3" />
C#
var paths = new List<string>(ConfigurationManager.AppSettings["paths"].Split(new char[] { ';' }));
You could have them semi-colon delimited in a single value, e.g.
App.config
<add key="paths" value="C:\test1;C:\test2;C:\test3" />
C#
var paths = new List<string>(ConfigurationManager.AppSettings["paths"].Split(new char[] { ';' }));