You can’t do that with a LINQ joins – LINQ only supports equijoins. However, you can do this:
var query = from e in entity.M_Employee
from p in entity.M_Position
where e.PostionId >= p.PositionId
select p;
Or a slightly alternative but equivalent approach:
var query = entity.M_Employee
.SelectMany(e => entity.M_Position
.Where(p => e.PostionId >= p.PositionId));