Could pandas use column as index?

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Yes, with set_index you can make Locality your row index.

data.set_index('Locality', inplace=True)

If inplace=True is not provided, set_index returns the modified dataframe as a result.

Example:

> import pandas as pd
> df = pd.DataFrame([['ABBOTSFORD', 427000, 448000],
                     ['ABERFELDIE', 534000, 600000]],
                    columns=['Locality', 2005, 2006])

> df
     Locality    2005    2006
0  ABBOTSFORD  427000  448000
1  ABERFELDIE  534000  600000

> df.set_index('Locality', inplace=True)
> df
              2005    2006
Locality                  
ABBOTSFORD  427000  448000
ABERFELDIE  534000  600000

> df.loc['ABBOTSFORD']
2005    427000
2006    448000
Name: ABBOTSFORD, dtype: int64

> df.loc['ABBOTSFORD'][2005]
427000

> df.loc['ABBOTSFORD'].values
array([427000, 448000])

> df.loc['ABBOTSFORD'].tolist()
[427000, 448000]

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