First, scale Rate
by Rate*max(df$Response)
and modify the 0.9
scale of Response text.
Second, include a second axis via scale_y_continuous(sec.axis=...)
:
ggplot(df) +
geom_bar(aes(x=Year, y=Response),stat="identity", fill="tan1", colour="sienna3")+
geom_line(aes(x=Year, y=Rate*max(df$Response)),stat="identity")+
geom_text(aes(label=Rate, x=Year, y=Rate*max(df$Response)), colour="black")+
geom_text(aes(label=Response, x=Year, y=0.95*Response), colour="black")+
scale_y_continuous(sec.axis = sec_axis(~./max(df$Response)))
Which yields: