Beginning with MySQL 8.0.19 you can use an alias for that row (see reference).
INSERT INTO beautiful (name, age)
VALUES
('Helen', 24),
('Katrina', 21),
('Samia', 22),
('Hui Ling', 25),
('Yumie', 29)
AS new
ON DUPLICATE KEY UPDATE
age = new.age
...
For earlier versions use the keyword VALUES
(see reference, deprecated with MySQL 8.0.20).
INSERT INTO beautiful (name, age)
VALUES
('Helen', 24),
('Katrina', 21),
('Samia', 22),
('Hui Ling', 25),
('Yumie', 29)
ON DUPLICATE KEY UPDATE
age = VALUES(age),
...