Do it like this :
String folder_main = "NewFolder";
File f = new File(Environment.getExternalStorageDirectory(), folder_main);
if (!f.exists()) {
f.mkdirs();
}
If you wanna create another folder into that :
File f1 = new File(Environment.getExternalStorageDirectory() + "https://stackoverflow.com/" + folder_main, "product1");
if (!f1.exists()) {
f1.mkdirs();
}